Hazard class · Division guide

Toxic / Poison (Class 6.1) Storage

Class 6.1 covers toxic substances that can cause serious harm through inhalation, ingestion, or absorption. Many also carry a subsidiary flammable or corrosive hazard.

Class, Division, and GHS meaning

In DOT nomenclature, Class 6 is toxic/infectious materials and Division 6.1 is poisonous materials. When a chemical is listed as “Class 6.1, Division 3,” Class 6.1 is the primary hazard and Division/Class 3 usually signals a flammable-liquid subsidiary risk. Storage must address both.

Storage implications for rental buildings

Prioritize containment, access control, and segregation from food, incompatible chemicals, and high-occupancy areas. If the material is also flammable, choose fire-rated hazmat storage sized for the primary toxic risk and the fire load.

Flammable vs non-flammable within this class

Chemicals in this category (16)

Mapped from free-text hazard class values in Chemical DB. Always verify against the manufacturer SDS.

  • Acetone Cyanohydrin(CH3)2C(OH)CNClass 6, Division 6.1
    Flammable hazardFlammable Storage
  • Acrolein, InhibitedC3H4OClass 6.1, Division 3
    Flammable hazardFlammable Storage
  • Allyl AlcoholC3H6OClass 6.1, Division 3
    Flammable hazardFlammable Storage
  • Allyl BromideC3H5BrClass 6.1, Division 2.1
    Flammable hazardFlammable Storage
  • Allyl ChlorocarbonateC4H5ClO2Class 6.1, Division 2.1
    Flammable hazardFlammable Storage
  • Aluminum PhosphideAlPHighly toxic
    Flammable hazardFlammable Storage
  • AmmoniaH3NToxic
    Flammable hazardFlammable Storage
  • AnilineC6H7N6.1
    Flammable hazardFlammable Storage
  • Arsenic PentafluorideAsF5Class 6.1, Division 2.3, Poison Gas
    Flammable hazardFlammable Storage
  • Arsenic PentoxideAs2O5Class 6.1, Division 6.1, Poison
    Non-flammableNon-Flammable Storage
  • Arsenic TrichlorideAsCl3Class 6.1, Division 6.1, Poison
    Flammable hazardFlammable Storage
  • Arsenic TrioxideAs2O3Class 6.1, Division 6.1, Poison
    Non-flammableNon-Flammable Storage
  • Ethyleneimine, InhibitedC2H5NO2Hazard Class 6.1: Flammable and Reactive Liquid
    Flammable hazardFlammable Storage
  • Lead ArsenatePbHAsO4Acute Tox. 3 H301 Toxic if swallowed. Acute Tox. 3 H331 Toxic if inhaled.
    Non-flammableNon-Flammable Storage
  • PhenolC6H6OAcute Toxiciy Category 3
    Non-flammableNon-Flammable Storage
  • Phenylmercuric Acetate, DryC8H8HgO2Acute Oral Toxicity Category 3
    Non-flammableNon-Flammable Storage